Dioxygen Activation by Non‐Adiabatic Oxidative Addition to a Single Metal Center
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چکیده
منابع مشابه
(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center
The first example of a transition metal (BB)-carboryne complex containing two boron atoms of the icosahedral cage connected to a single exohedral metal center (POBBOP)Ru(CO)2 (POBBOP = 1,7-OP(i-Pr)2-2,6-dehydro-m-carborane) was synthesized by double B-H activation within the strained m-carboranyl pincer framework. Theoretical calculations revealed that the unique three-membered (BB)>Ru metalacy...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2015
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.201508777